Defining and delineating the central areas of towns for statistical monitoring using continuous surface representations

The increasing availability of very high spatial resolution data using the unit postcode as its geo-reference is making possible new kinds of urban analysis andmodelling. However, at this resolution the granularity of the data used to representurban functions makes it difficult to apply traditional analytical and modellingmethods. An alternative suggested here is to use kernel density estimation totransform these data from point or area 'objects' into continuous surfaces of spatialdensities. The use of this transformation is illustrated by a study in which we attemptto develop a robust, generally applicable methodology for identifying the centralareas of UK towns for the purpose of statistical reporting and comparison.Continuous density transformations from unit post code data relating to a series ofindicators of town centredness created using ArcView are normalised and thensummed to give a composite ?Index of Town Centredness?. Selection of key contourson these index surfaces enables town centres to be delineated. The work results froma study on behalf of DETR

Nanoscale electrochemical patterning reveals the active sites for catechol oxidation at graphite surfaces

Graphite-based electrodes (graphite, graphene, and nanotubes) are used widely in electrochemistry, and there is a long-standing view that graphite step edges are needed to catalyze many reactions, with the basal surface considered to be inert. In the present work, this model was tested directly for the first time using scanning electrochemical cell microscopy reactive patterning and shown to be incorrect. For the electro-oxidation of dopamine as a model process, the reaction rate was measured at high spatial resolution across a surface of highly oriented pyrolytic graphite. Oxidation products left behind in a pattern defined by the scanned electrochemical cell served as surface-site markers, allowing the electrochemical activity to be correlated directly with the graphite structure on the nanoscale. This process produced tens of thousands of electrochemical measurements at different locations across the basal surface, unambiguously revealing it to be highly electrochemically active, with step edges providing no enhanced activity. This new model of graphite electrodes has significant implications for the design of carbon-based biosensors, and the results are additionally important for understanding electrochemical processes on related sp2-hybridized materials such as pristine graphene and nanotubes

All Sky Survey Mission Observing Scenario Strategy

This paper develops a general observing strategy for missions performing all-sky surveys, where a single spacecraft maps the celestial sphere subject to realistic constraints. The strategy is flexible such that targeted observations and variable coverage requirements can be achieved. This paper focuses on missions operating in Low Earth Orbit, where the thermal and stray-light constraints due to the Sun, Earth, and Moon result in interacting and dynamic constraints. The approach is applicable to broader mission classes, such as those that operate in different orbits or that survey the Earth. First, the instrument and spacecraft configuration is optimized to enable visibility of the targeted observations throughout the year. Second, a constraint-based high-level strategy is presented for scheduling throughout the year subject to a simplified subset of the constraints. Third, a heuristic-based scheduling algorithm is developed to assign the all-sky observations over short planning horizons. The constraint-based approach guarantees solution feasibility. The approach is applied to the proposed SPHEREx mission, which includes coverage of the North and South Celestial Poles, Galactic plane, and a uniform coverage all-sky survey, and the ability to achieve science requirements demonstrated and visualized. Visualizations demonstrate the how the all-sky survey achieves its objectives

Nanoscale intermittent contact-scanning electrochemical microscopy

A major theme in scanning electrochemical microscopy (SECM) is a methodology for nanoscale imaging with distance control and positional feedback of the tip. We report the expansion of intermittent contact (IC)-SECM to the nanoscale, using disk-type Pt nanoelectrodes prepared using the laser-puller sealing method. The Pt was exposed using a focused ion beam milling procedure to cut the end of the electrode to a well-defined glass sheath radius, which could also be used to reshape the tips to reduce the size of the glass sheath. This produced nanoelectrodes that were slightly recessed, which was optimal for IC-SECM on the nanoscale, as it served to protect the active part of the tip. A combination of finite element method simulations, steady-state voltammetry and scanning electron microscopy for the measurement of critical dimensions, was used to estimate Pt recession depth. With this knowledge, the tip-substrate alignment could be further estimated by tip approach curve measurements. IC-SECM has been implemented by using a piezo-bender actuator for the detection of damping of the oscillation amplitude of the tip, when IC occurs, which was used as a tip-position feedback mechanism. The piezo-bender actuator improves significantly on the performance of our previous setup for IC-SECM, as the force acting on the sample due to the tip is greatly reduced, allowing studies with more delicate tips. The capability of IC-SECM is illustrated with studies of a model electrode (metal/glass) substrate

Radio Pulse Properties of the Millisecond Pulsar PSR J0437-4715. I. Observations at 20cm

We present a total of 48 minutes of observations of the nearby, bright millisecond pulsar PSR J0437-4715 taken at the Parkes radio observatory in Australia. The data were obtained at a central radio frequency of 1380 MHz using a high-speed tape recorder that permitted coherent Nyquist sampling of 50 MHz of bandwidth in each of two polarizations. Using the high time resolution available from this voltage recording technique, we have studied a variety of single-pulse properties, most for the first time in a millisecond pulsar. We find no evidence for "diffractive" quantization effects in the individual pulse arrival times or amplitudes as have been reported for this pulsar at lower radio frequency using coarser time resolution (Ables et al. 1997). Overall, we find that the single pulse properties of PSR J0437-4715 are similar to those of the common slow-rotating pulsars, even though this pulsar's magnetosphere and surface magnetic field are several orders of magnitude smaller than those of the general population. The pulsar radio emission mechanism must therefore be insensitive to these fundamental neutron star properties.Comment: 24 Postscript pages, 11 eps figures. Accepted for publication in the Astrophysical Journal. Abbreviated abstract follow

Rural to Urban Migration and Changes in Cardiovascular risk Factors in Tanzania: A Prospective Cohort Study.

High levels of rural to urban migration are a feature of most African countries. Our aim was to investigate changes, and their determinants, in cardiovascular risk factors on rural to urban migration in Tanzania. Men and women (15 to 59 years) intending to migrate from Morogoro rural region to Dar es Salaam for at least 6 months were identified. Measurements were made at least one week but no more than one month prior to migration, and 1 to 3 monthly after migration. Outcome measures included body mass index, blood pressure, fasting lipids, and self reported physical activity and diet. One hundred and three men, 106 women, mean age 29 years, were recruited and 132 (63.2%) followed to 12 months. All the figures presented here refer to the difference between baseline and 12 months in these 132 individuals. Vigorous physical activity declined (79.4% to 26.5% in men, 37.8% to 15.6% in women, p < 0.001), and weight increased (2.30 kg men, 2.35 kg women, p < 0.001). Intake of red meat increased, but so did the intake of fresh fruit and vegetables. HDL cholesterol increased in men and women (0.24, 0.25 mmoll-1 respectively, p < 0.001); and in men, not women, total cholesterol increased (0.42 mmoll-1, p = 0.01), and triglycerides fell (0.31 mmoll-1, p = 0.034). Blood pressure appeared to fall in both men and women. For example, in men systolic blood pressure fell by 5.4 mmHg, p = 0.007, and in women by 8.6 mmHg, p = 0.001. The lower level of physical activity and increasing weight will increase the risk of diabetes and cardiovascular disease. However, changes in diet were mixed, and may have contributed to mixed changes in lipid profiles and a lack of rise in blood pressure. A better understanding of the changes occurring on rural to urban migration is needed to guide preventive measures

Electrochemistry, ion adsorption and dynamics in the double layer: a study of NaCl(aq) on graphite

Graphite and related sp2 carbons are ubiquitous electrode materials with particular promise for use in e.g., energy storage and desalination devices, but very little is known about the properties of the carbon–electrolyte double layer at technologically relevant concentrations. Here, the (electrified) graphite–NaCl(aq) interface was examined using constant chemical potential molecular dynamics (CμMD) simulations; this approach avoids ion depletion (due to surface adsorption) and maintains a constant concentration, electroneutral bulk solution beyond the surface. Specific Na+ adsorption at the graphite basal surface causes charging of the interface in the absence of an applied potential. At moderate bulk concentrations, this leads to accumulation of counter-ions in a diffuse layer to balance the effective surface charge, consistent with established models of the electrical double layer. Beyond ∼0.6 M, however, a combination of over-screening and ion crowding in the double layer results in alternating compact layers of charge density perpendicular to the interface. The transition to this regime is marked by an increasing double layer size and anomalous negative shifts to the potential of zero charge with incremental changes to the bulk concentration. Our observations are supported by changes to the position of the differential capacitance minimum measured by electrochemical impedance spectroscopy, and are explained in terms of the screening behaviour and asymmetric ion adsorption. Furthermore, a striking level of agreement between the differential capacitance from solution evaluated in simulations and measured in experiments allows us to critically assess electrochemical capacitance measurements which have previously been considered to report simply on the density of states of the graphite material at the potential of zero charge. Our work shows that the solution side of the double layer provides the more dominant contribution to the overall measured capacitance. Finally, ion crowding at the highest concentrations (beyond ∼5 M) leads to the formation of liquid-like NaCl clusters confined to highly non-ideal regions of the double layer, where ion diffusion is up to five times slower than in the bulk. The implications of changes to the speciation of ions on reactive events in the double layer are discussed

New Approach to Achieving Stand Alone GPS Attitude Determination using Dual Short Baselines for Small-Satellite

This paper proposes a new approach to GPS (Global Positioning System) attitude determination for small satellite application in LEO (low Earth orbit). Prior knowledge of attitude and integer resolution is not required. The methodology of the new approach includes integer ambiguity search, initial estimation of attitude and line bias, attitude initialisation, path difference estimation and fine attitude determination. The observable is the carrier phase difference measurement between two GPS antennas. A dual short baseline (typical baseline length up to 30 cm) is assumed in this research. The key point to initialising attitude is to estimated the attitude of individual baseline vectors with respect to the reference frame. Elimination of integer ambiguity is a simple task. Two set of vectors are required to determine an initial attitude. Once attitude is initialised, an estimation algorithm based on the extended Kalman filter starts to determine the attitude. The integer ambiguities and cycle slips can be resolved properly. The filter now is converged and, fine attitude is estimated. The robustness of the filtering estimator is tested with simulated anomalous conditions